Experimental Study on the Synthesis of Titanium and Tantalum Nitrides in the Self-Propagating Regime
作者:
CHRISTOSC. AGRAFIOTIS,
JANA. PUSZYNSKI,
VLADIMIRH. LAVACEK,
期刊:
Combustion Science and Technology
(Taylor Available online 1991)
卷期:
Volume 76,
issue 4-6
页码: 187-218
ISSN:0010-2202
年代: 1991
DOI:10.1080/00102209108951709
出版商: Taylor & Francis Group
关键词: Combustion synthesis;titanium nitride;tantalum nitride;activation energy
数据来源: Taylor
摘要:
A detailed experimental study of the synthesis of transition metal nitrides via combustion reactions between gaseous nitrogen and the respective metal powders at elevated pressures is presented. Two representative combustion reactions were studied: between tantalum and nitrogen, which proceeds without the formation of any liquid phase, and between titanium and nitrogen, which is accompanied by melling of the reactant titanium powder. The effects of nitrogen pressure, metal particle size, porosity of the metal sample and dilution of the solid phase on the combustion characteristics were studied and optimum conditions for the synthesis of the respective nitrides were determined. Values of the apparent activation energies for the two reactions were extracted, based on combustion characteristics measurements.
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