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Viscosity model for polydisperse polymer melts

 

作者: D. Nichetti,   I. Manas-Zloczower,  

 

期刊: Journal of Rheology  (AIP Available online 1998)
卷期: Volume 42, issue 4  

页码: 951-969

 

ISSN:0148-6055

 

年代: 1998

 

DOI:10.1122/1.550908

 

出版商: The Society of Rheology

 

关键词: Viscosity;Polydispersity;Molecular weight distribution

 

数据来源: AIP

 

摘要:

A simple superposition model was used to define the relationship between molecular weight distribution and shear viscosity for linear polymeric systems. Gel permeation chromatography data for molecular weight distributions were fitted using statistical distribution functions. A simple superposition model was then employed to calculate the shear viscosity for the systems investigated. The effect of polydispersity on the shape of the flow curves was calculated. The simplicity of the model makes feasible its use in numerical simulations of complex geometries as encountered in polymer processing equipment. The present study also sheds some light on the relationship between entanglement and disentanglement phenomena in polymeric systems.

 

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