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Contribution to a General Theory of Thermocouples

 

作者: A. H. Boerdijk,  

 

期刊: Journal of Applied Physics  (AIP Available online 1959)
卷期: Volume 30, issue 7  

页码: 1080-1083

 

ISSN:0021-8979

 

年代: 1959

 

DOI:10.1063/1.1776982

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Application of thermodynamics of irreversible processes to a thermocouple of which (a) the bars have an arbitrary shape, (b) the properties of the materials are arbitrary functions of temperature, and (c) the composition is, under certain restrictions, inhomogeneous and anisotropic, leads through introduction of a single place coordinate to two nonlinear differential equations describing the stationary distribution of temperature and electrical potential. Output powers and efficiencies are expressed in terms of the temperature gradients in the bars. The maximal values of the efficiencies obtained by variation of the shape of the bars are independent of the shape. Upper bounds of the efficiencies attainable by stationary thermoelectric conversion are derived. If the shape of the bars is restricted to general cylinders and truncated wedges or cones the transient behavior is described by two partial differential equations which contain two independent variables only. A periodic ripple in the electrical current has the same effect as a decrease of the electrical conductivities of the materials.

 

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