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Base-Catalyzed Rate and Arrhenius Activation Energy fort-Butyl Isothiocyanate Hydrolysis in Dioxane-H2O and Ethanol-H2O Mixtures by Gas Chromatography

 

作者: E.D. Moorhead,   J.A. Carlton,  

 

期刊: Analytical Letters  （Taylor Available online 1971）
卷期: Volume 4, issue 11  

页码: 715-726

 

ISSN:0003-2719

 

年代: 1971

 

DOI:10.1080/00032717108058671

 

出版商: Taylor & Francis Group

 

关键词: Hydrolysis;t-Butyl Isothiocyanate;Rate;Gas Chromatography

 

数据来源: Taylor

 

摘要:

N-bondedtertiary-butyl isothiocyanate hydrolyzesviaa mechanism that differs from the normal, or S-bonded linkage isomer. The diminutive amount of published kinetic data for the former compound prompted a redetermination of the base-catalyzed rate of hydrolysis of the isothiocyanate in 2% dioxane, ethanol water mixtures at several temperatures using gas-liquid chromatography.

 

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