Spectrophotometric Determination of the Platinum Metals I. The Determination of Tervalent Rhodium with Eriochromcyanine R in the Presence of Cetylpyridinium Bromide
作者:
H. Duchková,
L. Ĉermáková,
M. Malát,
期刊:
Analytical Letters
(Taylor Available online 1975)
卷期:
Volume 8,
issue 2
页码: 115-122
ISSN:0003-2719
年代: 1975
DOI:10.1080/00032717508058469
出版商: Taylor & Francis Group
关键词: spectrophotometry analysis;rhodium;eriochromcyanine R;cetylpyridinium bromide
数据来源: Taylor
摘要:
A new photometric method is described for the determination of microgram amounts of Rh(III), based on the formation of a ternary complex of the metal, eriochromcyanine R and cetylpyridinium bromide in an acetate buffer medium (pH = 3.2 - 3.6) with an absorption maximum at 600 nm. The system obeys the Lambert-Beer law for 0. 2 - 3. 2 ppm Rh(III). The mean relative standard deviation is 0. 66%, the molar absorptivity at 630 nm, the wavelength of the maximum difference between the ternary 4 solution and a solution of the reagents, is 1.2 × 104and the detection limit of the method is 7.8 μg. cm−2for A = 0. 001.
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