Mechanism of phosphite stabilizers in polyolefins subjected to ultraviolet irradiation
作者:
G. V. Hutson,
G. Scott,
期刊:
Journal of Polymer Science: Polymer Symposia
(WILEY Available online 1973)
卷期:
Volume 40,
issue 1
页码: 67-71
ISSN:0360-8905
年代: 1973
DOI:10.1002/polc.5070400109
出版商: Wiley Subscription Services, Inc., A Wiley Company
数据来源: WILEY
摘要:
AbstractThe effect of thermal‐oxidative processing on the stability to ultraviolet irradiation of high density polyethylene containing a catechol hindered‐phenyl phosphite has been studied by periodic observation of carbonyl index by infrared spectrometry and by recording embrittlement times.Certain of the possible thermal‐oxidative reaction products of catechol hindered‐phenyl phosphite, catechol hindered‐phenyl phosphate and mono‐(σ‐hydroxyphenyl)phosphoric acid have also been studied. The results are consistent with the theory previously developed that the latter or its dehydration product, catechol hydroxy phosphate, is the effective antioxidant produced dur
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