Chemiluminescence Determination of Sulfur Dioxide in Air Using Tris(1,10-Phenanthroline)Ruthenium−KIO4System
作者:
Zhike He,
Fengwu Wu,
Hui Meng,
Liangjie Yuan,
Qingyao Luo,
Yun'e Zeng,
期刊:
Analytical Letters
(Taylor Available online 1999)
卷期:
Volume 32,
issue 2
页码: 401-410
ISSN:0003-2719
年代: 1999
DOI:10.1080/00032719908542828
出版商: Taylor & Francis Group
关键词: Sulfite;Chemiluminescence;tris(1, 10-phenanthroline)ruthenium(II), air
数据来源: Taylor
摘要:
The emission produced by sulfite in its oxidation by periodate in acidic solution in the presence of Ru(phen)32+is used to determine 1.0x10−7to 1.5x10−4mol/L sulfite. The limit of detection is 7x10−10mol/L and the relative standard deviation is 2.3% for a 4x10−5mol/L sulfite solution (n=9). The method was applied satisfactorily to the determination of sulfur dioxide in air by using triethanolamine (TEA) as absorbent material.
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