Physicochemical Characterization of Poly(vinyl chloride). II. Molecular Weight Distributions
作者:
M.D. Baijal,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1968)
卷期:
Volume 2,
issue 5
页码: 1055-1063
ISSN:0022-233X
年代: 1968
DOI:10.1080/10601326808051456
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Molecular weight distributions in poly(vinyl chloride) resins have been determined from simple viscosity measurements. Ratio of 11% solution viscosity to intrinsic viscosity yielded a figure which has been correlated with molecular weight distributions obtained (1) from the ratio of weight-average to number-average molecular weights and (2) from gel permeation chromatography. Ratio of viscosities is thus a useful short-cut technique for obtaining approximate molecular weight distributions in poly(vinyl chloride) resins which have 0. 77 < [η] < 1.15 and 1. 6 < ROM < 2. 8.
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