Aqueous Polymerization of Acrylonitrile Initiated by Potassium Bromate-Thioacetamide Redox System
作者:
Nilambar Baral,
NrusinghaC. Pati,
PadmaL. Nayak,
SudhansuB. Dash,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1982)
卷期:
Volume 18,
issue 4
页码: 545-553
ISSN:0022-233X
年代: 1982
DOI:10.1080/00222338208082067
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The polymerization of acrylonitrile initiated by potassium bromate coupled with thioacetamide was investigated in aqueous solution under nitrogen atmosphere. The effect of monomer, initiator, activator, and acid concentration on the rate of polymerization as well as on maximum conversion was evaluated. The rate of polymerization was found to increase up to 1.25 × 10−3Mof initiator concentration and thereafter it decreased. The rate of polymerization also increased with the monomer and activator concentration up to 1.5078 and 4.0 × 10−3M, respectively, after which the rate fell. The effect of acid concentration, temperature, and solvents on rate of polymerization has been studied and a suitable kinetic scheme has been pictured.
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