E.S.R. studies of excited states in solution
作者:
C.D. Buckley,
K.A. McLauchlan,
期刊:
Molecular Physics
(Taylor Available online 1985)
卷期:
Volume 54,
issue 1
页码: 1-22
ISSN:0026-8976
年代: 1985
DOI:10.1080/00268978500100011
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The observation of electron spin polarized spectra from free radicals using flash-photolysis electron spin resonance methods is described. The origins of polarization are summarized and a critical account of their present understanding provided. The phases of the polarized signals carry information on the multiplicity of the radical precursor. Examples are provided from observations of nitrogen heterocyclic radicals of the use of the spectra to obtain such information, and to identify reactive states precisely.
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