Induced circular dichroism of biphenyl and its derivatives in mesophase
作者:
Yukio Sato,
Akio Tajiri,
Masahiro Hatano,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 4
页码: 989-996
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021830422
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe mesophase induced circular dichroism (CD) of biphenyl and its derivatives was investigated using the Tween 80 (monooleate of the ether of sorbitan with 4 mol of polyethyleneglycol)‐water system, which can form a twisted smectic mesophase. The sign of CD bands in this mesophase is explained by a modified C2‐symmetry rule, since it can be considered that alignment of the solute molecules in this mesophase can be elucidated in terms of a pseudo‐C2symmetry, when the concentration of the solute is comparatively high. The assignments of the electronic transitions of the solute molecules show a good accordance with results of magnetic circular dichroism
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