Artifact Formation In The Soxhlet Extraction Of Environmental Samples With Acetone
作者:
ArthurL. Lafleur,
Nicholas Pangaro,
期刊:
Analytical Letters
(Taylor Available online 1981)
卷期:
Volume 14,
issue 19
页码: 1613-1624
ISSN:0003-2719
年代: 1981
DOI:10.1080/00032718108059825
出版商: Taylor & Francis Group
关键词: Artifact formation;acetone derivatives;isophorone;phorone;mesitylene;diacetone alcohol;mesityl;oxide;gas chromatographic mass spectrometry (GC/MS)
数据来源: Taylor
摘要:
A study was performed to confirm suspected artifactual formation of acetone derivatives during the Soxhlet extraction of soil samples with acetone. The conditions employed simulated very closely those normally employed for the extraction of soils for neutral and moderately polar organic compounds such as pesticides. A series of acidic, neutral, and basic organic-free soils were extracted with hexane/acetone solvent mixture and the extracts concentrated in a Kuderna-Danish apparatus. The extracts were analyzed by capillary column gas chromatographic mass spectrometry. In nearly all cases, simple dimeric products such as diacetonecohol and mesityl oxide were formed in varying amounts. The acidified and basic soils yielded complex mixtures of dimers, trimers, tetramers and other complex homologs. Some of the more common substances found include phorone, mesitylene and isophorone. The latter substance is listed as an EPA priority pollutant.
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