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Neighbouring group participation in the photolysis of aryl esters of unsaturated 1,4‐dicarboxylic acids

 

作者: M. Alvaro,   H. Garcia,   J. Primo,   M. A. Miranda,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  （WILEY Available online 1986）
卷期: Volume 105, issue 7‐8  

页码: 233-234

 

ISSN:0165-0513

 

年代: 1986

 

DOI:10.1002/recl.19861050709

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractPhotolysis of the aryl maleates la,b produces homolysis of the carbonyl‐aryloxy bond, followed by internal addition of the acyl radical to the neighbouring carbonyl group, giving the unexpected products 3 or 4; by contrast the aryl fumarates 2a,b follow the “normal” photo‐Fries

 

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