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E.F.R and Spectroscopic Studies of Cu(3-Piooline)2(N3)2Crystal

 

作者: S. Bedewy,   M.A. S. Goher,   S.K. Hoffmann,   L.S. Szcespaniak,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1987）
卷期: Volume 20, issue 3  

页码: 221-231

 

ISSN:0038-7010

 

年代: 1987

 

DOI:10.1080/00387018708081545

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

EPR, UV-Vie, and IR measurements were performed to determine the molecular structure of Cu(3-picoline)2(N3)2in solid state. Single crystal EPR spectra indicate non-coupled copper (I1) complexes with gn= 2.265 and g⊥= 2.056. A binuclear complex structure is suggested with end-to-end azido copper (I1) bibridges which are not optimiaed for exchange coupling transmission.

 

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