The EPR Spectrum of Di-μ-(pyridine N-oxide) bis [bisnitrato(pyridine N-oxide)copper(II)] in the Corresponding Zinc(II) Crystal
作者:
KennethT. McGregor,
WilliamE. Hatfield,
期刊:
Spectroscopy Letters
(Taylor Available online 1975)
卷期:
Volume 8,
issue 8
页码: 571-576
ISSN:0038-7010
年代: 1975
DOI:10.1080/00387017508067361
出版商: Taylor & Francis Group
关键词: Copper(II);Dimers;Pyridine N-oxide;EPR.
数据来源: Taylor
摘要:
It has been shown1–3that the exchange interactions in the dimeric4complex di-μ-(pyridine N-oxide) bis [bisnitrato(pyridine N-oxide) copper(II)], [Cu(pyO)2]2lead to a triplet ground state for the copper(II) pairs. The triplet state epr spectrum has been observed1,3,5,6for a powdered sample of the complex coprecipitated with the corresponding zinc(II) complex, and the computer simulation of this spectrum has been carried out by two different groups3,5,6. As is often the case when dealing with spectra of powdered samples, there exist ambiguities with the spectrum of [Cu(pyO)2-(NO3)2]2since all of the resonances were not observed, and consequently, the interpretation and values of the parameters remain in question. It was felt that examination of the epr spectra of single crystal samples should permit a rigorous analysis of this problem.
点击下载:
PDF (184KB)
返 回