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The influence of substituents on the geometry of the cyclopropane ring. V. The molecular and crystal structure of 1‐amino‐1‐methylcyclopropane

 

作者: J. S. A. M. de Boer,   C. H. Stam,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  （WILEY Available online 1991）
卷期: Volume 110, issue 7‐8  

页码: 317-318

 

ISSN:0165-0513

 

年代: 1991

 

DOI:10.1002/recl.19911100703

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractCrystals of 1‐amino‐1‐methylcyclopropane, C4H9N, grown from the liquid, are tetragonal, space groupI41/a, a= 18.142(3),c= 5.882(1) Å, (169K),Z= 16. The finalRfor 733 independent observed reflections is 0.040. The molecule has thes‐transpyramidal conformation for the amino group. The bond‐length asymmetry induced by the substituents is small and about equal to that in aminocyclopropane. The average CC bond length is 1.513 Å (corrected f

 

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