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Vinyl Polymerization. 254.* Polymerization of Methyl Methacrylate by the System Cellulose-Water-Carbon Tetrachloride

 

作者: M. Imoto,   M. Kinoshita,   Y. Iki,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1971)
卷期: Volume 5, issue 2  

页码: 287-296

 

ISSN:0022-233X

 

年代: 1971

 

DOI:10.1080/00222337108069381

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Radical polymerization of methyl methacrylate initiated by the system cellulose-water-carbon tetrachloride was kinetically studied. Results obtained are: 1) The amounts of water, carbon tetrachloride, and cellulose affected the conversion. Michaelis-Menten's equation was applied to the relationship between the rate of polymerization and the amount of MMA. 2) Other methacrylates and acrylates were also polymerized by this system. 3) When methanol or ethanol was used instead of water, some weak polymerization activity was observed. 4) Initiating ability depended on the kind of cellulose used. 5) The activity of cellulose was not changed by washing with boiling water or by solvent extraction. 6) Polymerization was inhibited by the presence of air. 7) Heating in the presence of water and carbon tetrachloride markedly decreased the activity of the cellulose.

 

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