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Magnetism of Pyrimidine-Bridged Metal(II) Halide Complexes

 

作者: Kenji Zusai,   Takaharu Kusaka,   Takayuki Ishida,   Ralf Feyerherm,   Michael Steiner,   Takashi Nogami,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 343, issue 1  

页码: 127-132

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008023514

 

出版商: Taylor & Francis Group

 

关键词: weak ferromagnet;canted antiferromagnet;X-ray diffraction;neutron diffraction

 

数据来源: Taylor

 

摘要:

Magnetic phase transitions of PM2·CoCl2, PM2·CoBr2, and PM2·FeCl2(PM = pyrimidine) were observed atTN= 4.4, 4.7, and 6.1 K, respectively, as defined by the peak of χac′. They are characterized to be isomorphous, belonging to the space groupI4122, and canted antifer-romagnets belowTN. The neutron diffraction study supports the principally antiferromagnetic structure.

 

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