THE REACTION BETWEEN METHYL RADICALS AND ISOBUTANE
作者:
A. R. Blake,
J. F. Henderson,
K. O. Kutschke,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1961)
卷期:
Volume 39,
issue 10
页码: 1920-1928
ISSN:0008-4042
年代: 1961
DOI:10.1139/v61-258
出版商: NRC Research Press
数据来源: NRC
摘要:
It has been confirmed that the apparent rate constant for the reaction between methyl radicals, produced by the photolysis of deuterated acetone, and isobutane increases with decreasing isobutane pressure. An explanation is proposed to account for this observation suggesting that the production of methane by disproportionation between methyl andt-butyl radicals was not negligible as has been assumed previously.
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