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Electro-optical properties of 4,4-bis-[omega-(4-cyanobiphenyl-4yloxy)alkyloxy]biphenyls nematics

 

作者: NIKOLAIV. TSVETKOV,   VJACHESLAVV. ZUEV,   VICTORN. TSVETKOV,  

 

期刊: Liquid Crystals  (Taylor Available online 1997)
卷期: Volume 22, issue 3  

页码: 245-253

 

ISSN:0267-8292

 

年代: 1997

 

DOI:10.1080/026782997209298

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Electro-optical properties of nematics of the trimer series 4,4-bis-[omega-(4-cyanobiphenyl-4yloxy)alkyloxy]biphenyls have been investigated by the method of orientational elastic deformations in electric fields. The number n of CH2 groups in the oxyalkyl fragment was varied from n 2 to n 10. A strong odd-even effect was observed in the optical anisotropy Deltan and in the values of the threshold potential V0 for the trimer nematics. These effects are, respectively, caused by oscillations of the degree of inter- and intra-molecular orientational order when n is varied. The great difference in the dependences of Deltan and V0 on n is discussed and compared with data for dimers.

 

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