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Definition of the Perfect Gas and Its Relation to the Second Law of Thermodynamics

 

作者: Donald G. Miller,   Warren Dennis,  

 

期刊: American Journal of Physics  （AIP Available online 1960）
卷期: Volume 28, issue 9  

页码: 796-798

 

ISSN:0002-9505

 

年代: 1960

 

DOI:10.1119/1.1936005

 

出版商: American Association of Physics Teachers

 

数据来源: AIP

 

摘要:

It is shown that a perfect gas must be defined by two independent statements. BesidesPV = nRT, either(δE/δV)T = 0orT = θmay be used. The proof shows that the second law will not yield(δE/δV)T = 0fromPV = nRTalone, and is given for both the Carnot cycle and Carathéodory formulations of the second law.

 

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