Cubic‐to‐Tetragonal (t') Transformation in Zirconia‐Containing Systems
作者:
Tzer‐Shin Sheu,
Tseng‐Ying Tien,
I‐Wei Chen,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1992)
卷期:
Volume 75,
issue 5
页码: 1108-1116
ISSN:0002-7820
年代: 1992
DOI:10.1111/j.1151-2916.1992.tb05546.x
出版商: Blackwell Publishing Ltd
关键词: zirconia;transformations;microstructure;phase diagrams;quenching
数据来源: WILEY
摘要:
The coexistence of the cubic fluorite and tetragonal phases in rapidly quenched samples was studied in the ZrO2‐MO1.5systems for M = Sc, In, Y, and rare earths (R). Spontaneous transformation from metastable cubic phase was triggered at room temperature by a mechanical force. Isolated tetragonal platelets in the cubic matrix were bounded by [101] habit planes and contained anti‐phase boundaries. The tetragonality decreased with stabilizer content and vanished at around 18 mol% for M = Y and R, 23 mol% for M = Sc, and 25 mol% for M = In, all at room temperature. With increasing temperature, the tetragonality initially increased because of anisotropic thermal expansion, then decreased rapidly, after reaching a maximum, as the temperature for the tetragonal‐to‐cubic transformation was approached. Being a first‐order martensitic transformation, the cubic‐to‐tetragonal transformation is accompanied by a discontinuous change of tetragonality and a hysteresis loop as the temperature or composition passes through the equi
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