Theoretical interpretation of the effect of mixture composition on separation of liquids in polymers
作者:
Morton Fels,
RobertY. M. Huang,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1971)
卷期:
Volume 5,
issue 1
页码: 89-109
ISSN:0022-2348
年代: 1971
DOI:10.1080/00222347108212522
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A theoretical interpretation for the permeation of binary organic liquid mixtures through polymer films is developed. The model is based on an extension of the free-volume theory for diffusion of organic substances in polymers and takes into account the effect of one component of the mixture on the diffusion of the other component. The calculated permeabilities are in reasonable agreement with experimentally measured data.
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