Study of the Co-intercalation of Lanthanide Chlorides and Yttrium Chloride into Graphite
作者:
Eberhard Stumpp,
Claus Ehrhardt,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 310,
issue 1
页码: 75-80
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808045317
出版商: Taylor & Francis Group
关键词: Graphite intercalation compounds;lanthanide trichlorides
数据来源: Taylor
摘要:
Graphite intercalation compounds (GICs) with the trichlorides of Y, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu have been prepared and characterized by chemical analysis and X-ray diffraction. Attempts to synthesize binary GICs with LaCl3, CeCl3, PrCl3, and NdCl3failed. By heating mixtures of YCl3+ LnCl3(Ln = La - Lu) with graphite ternary GICs were obtained. The molar ratios LnCl3:YCl3in the GICs were found to increase from La to Dy which runs parallel to the decrease in the ionic radii of the Ln3+ions.
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