Polymerization of lactams, 80.Anionic polymerization of lactams accelerated withN‐iminolactams, 1 2‐pyrrolidone
作者:
Jiří Brožek,
Petr Řehák,
Miroslav Marek,
Jan Roda,
Jaroslav Králíček,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1988)
卷期:
Volume 189,
issue 1
页码: 9-16
ISSN:0025-116X
年代: 1988
DOI:10.1002/macp.1988.021890102
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe anionic polymerization of 2‐pyrrolidone (PD) was initiated with the potassium salt of PD at 30–50°C and accelerated with the followingN‐iminolactams (NIL): 1‐(1‐pyrrolin‐2‐yl)‐2‐pyrrolidone(1), 1‐(1‐azacyclohept‐1‐en‐2‐yl)‐2‐pyrrolidone(2), 1‐(1‐azacyclonon‐1‐en‐2‐yl)‐2‐pyrrolidone(4), 1‐(1‐azacyclohept‐1‐en‐2‐yl)‐1‐ azacycloheptan‐2‐one(3)and 1‐(phenyliminomethyl)‐2‐pyrrolidone(5). The polymerizations exhibit formal kinetics of zero order with respect to the monomer with substantially differing apparent rate constants depending on the type of NIL used. The same limit conversions are attained in a
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