Die Zersetzung saurer, methanolischer Karl‐Fischer‐Lösungen
作者:
Wolfgang Fischer,
Konrad Beckenkamp,
期刊:
Journal für Praktische Chemie/Chemiker‐Zeitung
(WILEY Available online 1998)
卷期:
Volume 340,
issue 1
页码: 58-61
ISSN:0941-1216
年代: 1998
DOI:10.1002/prac.19983400109
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
The Decomposition of Acidic Karl Fischer Reagent in MethanolThe reaction between sulfur dioxide and iodine in methanol is started by traces of water in the solvent. Hydrogen iodide is formed and reacts with methanol to produce more water until all iodine is used up. An addition compound between iodine and hydrogen sulfite was found as an intermediate and characterized by Raman spectroscopy. Elementary sulfur is formed in a second reaction.
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