The Chemistry of Organofunctionalized Silicon Cubanes in Swelling Smectites
作者:
D. Petridis,
D. Gournis,
M.A. Karakassides,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 311,
issue 1
页码: 345-350
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808042409
出版商: Taylor & Francis Group
关键词: triphase reactions;smectite;intercalation;organosilicon oligomers
数据来源: Taylor
摘要:
The intercalation of a cubical octamer derived from the controlled hydrolysis of 3-aminopropyltriethoxysilane with smectite clays has been examined. The organosilicon cubanes are adsorbed in an amount that exceeds the cation exchange capacity of the mineral. The excess quantity is incorporated in the form of physically adsorbed ion pairs. The results suggest that the physically adsorbed ionpaired cubic units, participate in alkylation reactions affording the corresponding tetraalkylammonium derivatives under triphase conditions. The alkylated products were studied by chemical analysis, X-ray diffraction and FT-infrared spectroscopy.
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