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Dielectric study of the tilted columnar mesophase in three new chiral metallorganic discotic mesogens

 

作者: BEATRIZ PALACIOS,   M. ROSARIO DE LA FUENTE,   MIGUEL ANGEL PEREZ JUBINDO,   RAQUEL IGLESIAS,   JOSE LUIS SERRANO,   TERESA SIERRA,  

 

期刊: Liquid Crystals  (Taylor Available online 1998)
卷期: Volume 25, issue 4  

页码: 481-485

 

ISSN:0267-8292

 

年代: 1998

 

DOI:10.1080/026782998205994

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Chiral oxovanadium(IV), copper(II) and palladium(II) beta-diketonates show a room temperature tilted columnar mesophase (rectangular P21). The dielectric response of these compounds was measured in the frequency range 10-2-109Hz. Three different relaxation processes have been observed in the columnar phase. One of them is only present in this mesophase and we suggest that it is a Goldstone-like mode, similar to the one present in the helical SmC* phases. In our case the presence of the helix was confirmed by circular dichroism studies.

 

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