On the refractive indices, polarizabilities and order parameter of a nematic discogenic mixture
作者:
T.J. Phillips,
J.C. Jones,
期刊:
Liquid Crystals
(Taylor Available online 1994)
卷期:
Volume 16,
issue 5
页码: 805-812
ISSN:0267-8292
年代: 1994
DOI:10.1080/02678299408027851
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The phase diagram of a mixture of the discogens triphenylene hexa-n-heptanoate (HET7) and triphenylene hexa-(2-methyl-4-n-decyloxy)benzoate is presented. This mixture provides a more accessible nematic temperature range than was previously possible. The refractive indices of one mixture composition are measured and a rather small, negative birefringence found. The two-parameter Haller extrapolation method is used to calculate the molecular polarizability ratio Δα/α. This has a rather small magnitude compared with calamitic mesogens, although the individual polarizabilities are much larger, due to the greater molecular mass of these compounds. The calculated value of Δα/αis used to give the uniaxial orientational order parameterS, whose value is comparable to those of calamitic examples. Tabulated bond polarizability data are used to predict a value for Δα/α, which is found to be similar to the experimental result.
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