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Biaxial steady states and their stability in shear flows of liquid crystal polymers

 

作者: Qi Wang,  

 

期刊: Journal of Rheology  (AIP Available online 1997)
卷期: Volume 41, issue 5  

页码: 943-970

 

ISSN:0148-6055

 

年代: 1997

 

DOI:10.1122/1.550816

 

出版商: The Society of Rheology

 

关键词: Liquid crystalline polymer;Biaxiality;Stability;Closure approximations

 

数据来源: AIP

 

摘要:

The biaxiality of the steady state solutions and their stability to out-of-plane disturbances in shear flows of spatially homogeneous liquid crystal polymers using two approximate models, BMAB-Doi and BMAB-HL1, which are derived from the kinetic theory developed by Bhave et al. (1993) (BMAB) using the Doi and the first Hinch–Leal closure approximation, respectively, are studied. By casting the models in a novel biaxial representation of the orientation tensor with two built-in order parameters and a triad of directors, we show explicitly that the steady states of the BMAB models exhibit biaxial symmetry except for some uniaxial degeneracy at isolated Peclet numbers and polymer concentration values. Moreover, we obtain all the steady states in which two directors are confined to the shearing plane and analyze their stability with respect to both in-plane and out-of-plane disturbances. We find that (1) flow-aligning family is the unique stable solution family in the BMAB-Doi model, where two order parameters are of opposite signs; (2) the flow-aligning family in the BMAB-HL1 model is stable only in a finite range of polymer concentration0  10,which grows with respect to the Peclet number; (3) The loss-of-stability in the flow-aligning family atN=10is caused by a one-dimensional director rotational instability pertinent to the existence of the maximum allowable degree of orientation with respect to the flow-aligning major director,56,and is coincident with the change-of-sign behavior of the first normal stress difference and the smaller order parameter as well.

 

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