POLYMERIZATION OF STYRENE IN LOW INTERFACIAL TENSION MICROEMULSION-OIL-WATER THREE-PHASE SYSTEMS
作者:
F. M. Rabagliati,
A. C. Falcón,
D. A. González,
C. Martín,
R. E. Antón,
J. L. Salager,
期刊:
Journal of Dispersion Science and Technology
(Taylor Available online 1986)
卷期:
Volume 7,
issue 2
页码: 245-258
ISSN:0193-2691
年代: 1986
DOI:10.1080/01932698608943458
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Polymerization was carried out with surfactant-styrene-brine systems which were formulated for the attainement of ultra-low interfacial tension and three-phase behavior. An anionic-nonionic surfactant mixture was used to maintain the optimum formulation over a certain range of temperature. Dispersion polymerization experiments were carried out with the initiator either in water (persulfate) or in styrene (AIBN). The polymerization systems exhibited both rate of polymerization and molecular weight dependence on the amount of added initiator, but no autoacceleration was observed.
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