首页   按分类浏览 期刊浏览 卷期浏览 Acylation of silicohydrocarbons and synthesis of silicon-containing α-methylstyrenes
Acylation of silicohydrocarbons and synthesis of silicon-containing α-methylstyrenes

 

作者: E.A.Chernyshev,   É.N.Klyukina,   A.D.Petrov,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2004)
卷期: Volume 9, issue 9  

页码: 1488-1492

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00909813

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.Improvements were effected in the earlier method of acylation of aromatic silicohydrocarbons which enabled preparation of the corresponding ketones in yields of up to 70%.2.Benzyltrimethylsilane is acylated 24 times faster and β -phenylethyltrimethylsilane only 16 times faster than benzene. This effect is associated with conjugation of the Si-C bond with the aromatic ring in benzyltrimethylsilane.3.Some para -substituted silicon containing α-methylstyrenes have been synthesize

 

点击下载:  PDF (514KB)



返 回