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Synthesis of the Trisaccharide α-l-Rha-(1-2)-α-l-Rha-(1-2)-α-L-Rha with a Dioxolane-Type Spacer-Arm1

 

作者: JulioC.Castro Palomino,   MarylinHernandez Rensoli,   VicenteVerez Bencomo,  

 

期刊: Journal of Carbohydrate Chemistry  （Taylor Available online 1996）
卷期: Volume 15, issue 2  

页码: 137-146

 

ISSN:0732-8303

 

年代: 1996

 

DOI:10.1080/07328309608005434

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The trisaccharide α-L-Rha-(1-2)-α-L-Rha-(1-2)-α-L-Rha with a dioxolane-type spacer was obtained by using the trichloroacetimidate method in all of the glycosidation steps. After deprotection, the trisaccharide was coupled to BSA or KLH by reductive amination of the spacer aldehyde group.

 

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