首页   按字顺浏览 期刊浏览 卷期浏览 The Selective Formose Reaction in Dimethylformamide in the Presence of Vitamin B1
The Selective Formose Reaction in Dimethylformamide in the Presence of Vitamin B1

 

作者: Yoshihiro Shigemasa,   Hideki Matsumoto,   Yoshihiro Sasaki,   Nasuo Ueda,   Ruka Nakashima,   Ken-Ichi Harada,   Naohito Takeda,   Makoto Suzuki,  

 

期刊: Journal of Carbohydrate Chemistry  (Taylor Available online 1983)
卷期: Volume 2, issue 3  

页码: 343-348

 

ISSN:0732-8303

 

年代: 1983

 

DOI:10.1080/07328308308057879

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The formose which was obtained from formaldehyde in the presence of base was a mixture of sugars and sugar alcohols containing over 30 components. The formose reaction has drawn much attention for 122 years from several standpoints; the chemical synthesis of edible carbohydrates from C1compounds, an important process in the recycling of carbon sources during sustained space flights, and as a model for the prebiotic synthesis of monosaccharides. Nevertheless, because of the complexity of this product mixture (Fig. 1b), the formose reaction has not been completely elucidated and the product (so called formose) has not been useful yet. During the long formose history few products were isolated from the formose mixture and identified, except in work from our laboratories.

 

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