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A Short Synthesis of Gastrolactone

 

作者: C.Rikard Unelius,   Torbjörn Norin,   Piotr Prokopowicz,   Janusz Jurczak,  

 

期刊: Natural Product Letters  (Taylor Available online 1994)
卷期: Volume 5, issue 1  

页码: 61-68

 

ISSN:1057-5634

 

年代: 1994

 

DOI:10.1080/10575639408043936

 

出版商: Taylor & Francis Group

 

关键词: chrysomelid beetle;Gastrophysa cyanea;gastrolactone;gastrolactol;plagiodial;enal-enamine [2+4] cycloaddition;larval defensive secretion

 

数据来源: Taylor

 

摘要:

Gastrolactone, a component from the larval defensive secretion of the chrysomelid beetleGastrophysa cyanea, was synthesized in four steps from citral. The key step was an enal-enamine [2+4] cycloaddition. Gastrolactol, the lactol form of plagiodial, was an intermediate in the synthetic sequence.

 

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