KINETIC STUDIES OF A REDOX POLYMERIZATION
作者:
R. M. Brown,
C. A. Winkler,
期刊:
Canadian Journal of Chemistry
(NRC Available online 1953)
卷期:
Volume 31,
issue 1
页码: 13-22
ISSN:0008-4042
年代: 1953
DOI:10.1139/v53-004
出版商: NRC Research Press
数据来源: NRC
摘要:
Kinetic studies of a redox-initiated polymerization have indicated activation energies of 9.7 kcal. per mole for the decomposition of the initiating system, approximately 6 kcal. per mole for the propagation reaction, and 9.0 kcal. per mole for the consumption of MTM-4 in the emulsion system. Lower polymerization temperatures raised the gel point without shortening the polymer chains, apparently by decreasing the proportion of cross-linking to propagation reactions. Two types of nonmercaptan termination have been found to occur to appreciable extents: mutual termination of free radicals and a termination process involving the emulsifier.
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