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Calamitic Organometallic Liquid Crystals of β-Diketonate Dicarbonylrhodium(I) Complexes

 

作者: Wen Wan,   Ke-Qin Zhao,   Wen-Jie Guang,   Chun-Yan Wang,   Liang-Fu Zhang,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 1998）
卷期: Volume 317, issue 1  

页码: 83-91

 

ISSN:1058-725X

 

年代: 1998

 

DOI:10.1080/10587259808047107

 

出版商: Taylor & Francis Group

 

关键词: Organometallic complex;liquid crystal;β-diketone

 

数据来源: Taylor

 

摘要:

A series of new rodlike organometallic complexes based on the β-diketone ligands with terminal metal have been synthesized. The mesomorphism of the ligands and complexes has been investigated using DSC and polarizing microscopy. Most of the complexes display nematic mesogenic behavior identically with that exhibited by ligands. The effect of the carbon number of the terminal chain on the mesomorphism is discussed.

 

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