首页   按字顺浏览 期刊浏览 卷期浏览 Activation parameters for transport and thermal expansion
Activation parameters for transport and thermal expansion

 

作者: Robert A. Stairs,  

 

期刊: Canadian Journal of Chemistry  (NRC Available online 1981)
卷期: Volume 59, issue 14  

页码: 2170-2172

 

ISSN:0008-4042

 

年代: 1981

 

DOI:10.1139/v81-312

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

A correlation is proposed between the ratios:Y = πΔV≠/E(p)≠(where π is the internal pressure of a liquid, ΔV≠the volume of activationRT(∂ ln η/∂p)T, andE(p)≠the activation energy at constant pressure for viscous flow, or the corresponding quantities for diffusion) andX = E(ρ)≠/E(p)(whereE(ρ)is the "energy of thermal expansion", defined by:−R[∂ ln (ρ−1 − ρ0−1)/∂T−1]p). The first,Y, involves quantities measured at high pressures, whileXrequires only measurements at ordinary pressure. The correlation will permit estimation of viscosities and diffusion coefficients at high pressures from low-pressure measurements.

 

点击下载:  PDF (201KB)



返 回