Surface and colloid properties of cyclic amides III. Surface activity and micellization of N-butyl-2-pyrrolidone in water
作者:
Anjing Lou,
BrianA. Pethica,
P. Somasundaran,
Aixing Fan,
期刊:
Journal of Dispersion Science and Technology
(Taylor Available online 1999)
卷期:
Volume 20,
issue 1-2
页码: 569-580
ISSN:0193-2691
年代: 1999
DOI:10.1080/01932699908943808
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The aggregation and surface activity of N-butyl-2-pyrrolidone (BP) in water is investigated using surface tension, solubilization, fluorescence and NMR methods. The micelle point is high (˜1.0 M) as expected for the butyl chain length, and the aggregation number is approximately 5, with pre-association below the c.m.c. Despite the low aggregation number, the fluorescence data indicate that the interior of the aggregate is similar to pure liquid BP. The adsorption of BP at the solution/air interface goes to a maxmum near the c.m.c, corresponding to an area of 45 ± 1 Å2/molecule.
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