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Creep and Recovery Properties of a Zinc Phosphinate Polymer

 

作者: D. J. Plazek,  

 

期刊: Transactions of the Society of Rheology  (AIP Available online 1965)
卷期: Volume 9, issue 1  

页码: 119-134

 

ISSN:0148-6055

 

年代: 1965

 

DOI:10.1122/1.549010

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

The investigation of the torsional creep and recovery behavior of a coordination polymerZn[OP(Ph)(Me)O]2at five temperatures from 100 to 200°C has revealed an unusual rheological behavior. A high temperature aging effect which appears at least partially reversible is observed. Observed creep deformation which is linear in time, followed by a delayed recovery, is explained as a consequence of a void in the retardation spectrum. Temperature reduction is achieved and the temperature shift factors are analyzed in the light of the WLF equation. The measurements were made with a recently developed creep instrument which employs a magnetically levitated rotor and a drag cup motor for precision torque production.

 

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