Creep and Recovery Properties of a Zinc Phosphinate Polymer
作者:
D. J. Plazek,
期刊:
Transactions of the Society of Rheology
(AIP Available online 1965)
卷期:
Volume 9,
issue 1
页码: 119-134
ISSN:0148-6055
年代: 1965
DOI:10.1122/1.549010
出版商: The Society of Rheology
数据来源: AIP
摘要:
The investigation of the torsional creep and recovery behavior of a coordination polymerZn[OP(Ph)(Me)O]2at five temperatures from 100 to 200°C has revealed an unusual rheological behavior. A high temperature aging effect which appears at least partially reversible is observed. Observed creep deformation which is linear in time, followed by a delayed recovery, is explained as a consequence of a void in the retardation spectrum. Temperature reduction is achieved and the temperature shift factors are analyzed in the light of the WLF equation. The measurements were made with a recently developed creep instrument which employs a magnetically levitated rotor and a drag cup motor for precision torque production.
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