Influence of Temperature and Polarity of the Medium on Rate and Equilibrium Constants in the Cationic Polymerization of Tetrahydrofuran
作者:
Krzysztof Matyjaszewski,
Marek Zielinski,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1979)
卷期:
Volume 13,
issue 2
页码: 193-202
ISSN:0022-233X
年代: 1979
DOI:10.1080/00222337908066597
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The propagation step of the polymerization process of tetrahydrofuran was studied in detail. The influence of temperature and dielectric constant of the reaction medium on the rate and equilibrium constants of the elementary steps of the reaction was investigated. As the changes of temperature result in changes of the dielectric constant of the medium, it was found necessary to give the dependence of the reaction constants on both these parameters simultaneously.
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