首页   按字顺浏览 期刊浏览 卷期浏览 Preparation and Properties of Gold Complexes with TTF Dithiolato Ligands
Preparation and Properties of Gold Complexes with TTF Dithiolato Ligands

 

作者: Yohji Misaki,   Yoshihiro Tani,   Masateru Taniguchi,   Tatsuyuki Maitani,   Kazuyoshi Tanaka,   Klaus Bechgaard,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 343, issue 1  

页码: 59-64

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008023503

 

出版商: Taylor & Francis Group

 

关键词: bis(dithiolene) complex;tetrathiafulvalene;gold complex;electrical conductivity;X-ray structure analysis

 

数据来源: Taylor

 

摘要:

Several gold(III) complexes with TTF dithiolato ligands have been prepared as the tetrahexylammonium salts. The cyclic voltammograms in DMF showed two or three pairs of redox waves. X-Ray structure analysis of Ph4P·Au(eodt)2·(DMF)2reveals that the Au(eodt)2anion takes a significantly folded chair conformation. Charge-transfer salts of Au(dt)2derivatives with TCNQ showed high conductivity (σrt= 100−101S cm−1on a compressed pellet).

 

点击下载:  PDF (209KB)



返 回