Sorption, Desorption, and Diffusion of Haloalkanes into Miscible Polymeric Blends of Ethylene-Propylene Random Copolymer and Isotactic Polypropylene
作者:
TejrajM. Aminabhavi,
HemantT. S. Phayde,
Chris Elliff,
Ajoy Rao,
期刊:
Polymer-Plastics Technology and Engineering
(Taylor Available online 1996)
卷期:
Volume 35,
issue 1
页码: 121-138
ISSN:0360-2559
年代: 1996
DOI:10.1080/03602559608000084
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Molecular transport of haloalkanes into polymeric blend sheets of ethylene-propylene random copolymer and isotactic polypropylene, Santoprene, has been investigated gravimetrically in the temperature interval 25°-70°C. Equilibrium sorption, desorption, resorption, redesorption, and degree of penetrant overshoot were influenced by the type of haloalkane used and the experimental temperature. Diffusion coefficients have been computed for the sorption (S), desorption (D), resorption (RS), and redesorption (RD) runs. Temperature-dependent sorption and diffusion coefficients were analyzed using the Arrhenius relation. Santo-prene-haloalkane interactions have been discussed in terms of sorption, desorption, and diffusion coefficients.
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