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Sorption, Desorption, and Diffusion of Haloalkanes into Miscible Polymeric Blends of Ethylene-Propylene Random Copolymer and Isotactic Polypropylene

 

作者: TejrajM. Aminabhavi,   HemantT. S. Phayde,   Chris Elliff,   Ajoy Rao,  

 

期刊: Polymer-Plastics Technology and Engineering  (Taylor Available online 1996)
卷期: Volume 35, issue 1  

页码: 121-138

 

ISSN:0360-2559

 

年代: 1996

 

DOI:10.1080/03602559608000084

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Molecular transport of haloalkanes into polymeric blend sheets of ethylene-propylene random copolymer and isotactic polypropylene, Santoprene, has been investigated gravimetrically in the temperature interval 25°-70°C. Equilibrium sorption, desorption, resorption, redesorption, and degree of penetrant overshoot were influenced by the type of haloalkane used and the experimental temperature. Diffusion coefficients have been computed for the sorption (S), desorption (D), resorption (RS), and redesorption (RD) runs. Temperature-dependent sorption and diffusion coefficients were analyzed using the Arrhenius relation. Santo-prene-haloalkane interactions have been discussed in terms of sorption, desorption, and diffusion coefficients.

 

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