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Use of Copper (II) Ion-Selective Electrode and Gran's Plots in the Sequential Complexometric Determination of Copper (II), Zinc (II) and Iron (III)

 

作者: R. Stella,   M.T. Ganzerli Valentini,   P.A. Borroni,  

 

期刊: Analytical Letters  (Taylor Available online 1984)
卷期: Volume 17, issue 6  

页码: 433-445

 

ISSN:0003-2719

 

年代: 1984

 

DOI:10.1080/00032718408065291

 

出版商: Taylor & Francis Group

 

关键词: Copper determination;iron determination;copper;zinc and iron in sequence;copper ion-selective electrode;Gran's plots

 

数据来源: Taylor

 

摘要:

A sequential chelometric determination of copper (II) and iron (III) is reported utilizing copper (II) ion-selective electrode (Cu-ISE) for detecting end points and Gran's plots for extending sensitivity to the level of 0.4 umole in 100 mL for each metal. A modified procedure is also suggested and described for samples in which interfering divalent ions, such as zinc (II), are present. Practical applications are reported.

 

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