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Modified cox-merz rule for charged polymer systems in solution

 

作者: K.C. Tam,   C. Tiu,  

 

期刊: Journal of Macromolecular Science, Part B  (Taylor Available online 1994)
卷期: Volume 33, issue 2  

页码: 173-184

 

ISSN:0022-2348

 

年代: 1994

 

DOI:10.1080/00222349408248086

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A simple technique is developed for predicting the dynamic viscosity from the steady shear viscosity data of polyelectrolyte solutions. The Carreau-type viscosity equation is used to represent both the steady shear and dynamic viscosity data. A shift factor β, defined as the ratio of the dynamic time constant to the steady shear time constant, is introduced. This dimensionless parameter enables all the dynamic viscosity data to be shifted onto the steady shear viscosity curve. The parameter β correlates well with the zero shear viscosity and has the following form:

 

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