Modified cox-merz rule for charged polymer systems in solution
作者:
K.C. Tam,
C. Tiu,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1994)
卷期:
Volume 33,
issue 2
页码: 173-184
ISSN:0022-2348
年代: 1994
DOI:10.1080/00222349408248086
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A simple technique is developed for predicting the dynamic viscosity from the steady shear viscosity data of polyelectrolyte solutions. The Carreau-type viscosity equation is used to represent both the steady shear and dynamic viscosity data. A shift factor β, defined as the ratio of the dynamic time constant to the steady shear time constant, is introduced. This dimensionless parameter enables all the dynamic viscosity data to be shifted onto the steady shear viscosity curve. The parameter β correlates well with the zero shear viscosity and has the following form:
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