Domain size of dynamic heterogeneities in antiplasticized polycarbonate by proton spin diffusion
作者:
Yu Liu,
Paul T. Inglefield,
Alan A. Jones,
R. P. Kambour,
期刊:
Magnetic Resonance in Chemistry
(WILEY Available online 1994)
卷期:
Volume 32,
issue S1
页码: 18-22
ISSN:0749-1581
年代: 1994
DOI:10.1002/mrc.1260321306
出版商: John Wiley&Sons, Ltd.
关键词: NMR;1H NMR;Polycarbonate;Domains;Proton spin diffusion
数据来源: WILEY
摘要:
AbstractProton spin diffusion measurements were made using the Goldman—Shen technique of bisphenol‐A polycarbonate containing 10 wt% trioctyl phosphate at temperatures below the glass transition temperature. The proton lineshapes reveal the existence of dynamic heterogeneities in the glass and spin diffusion can be observed from the more mobile to the less mobile domain. The time‐scale for spin diffusion is 4–10 ms and the mobile domain size is estimated at 11 Å at 339 K. This estimate is consistent with a mobile domain of approximately two diluent molecules and 11 polymer repeat units. This grouping can be compared with the results of a statistical lattice model used to estimate local environments at this com
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