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Matrix Isolation ir Spectra of Methyl Acetate II.Stoechiometry of Methyl Acetate…H2O Complexes in AR Matrices. Comparison with Methyl Benzoate…H20

 

作者: P. Vandevyvere,   G. Maes,   Th. Zeegers-Huyskens,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1987）
卷期: Volume 20, issue 6-7  

页码: 461-478

 

ISSN:0038-7010

 

年代: 1987

 

DOI:10.1080/00387018708081568

 

出版商: Taylor & Francis Group

 

关键词: Matrix isolation;methyl acetate;hydrogen bonding;stoechiometry.

 

数据来源: Taylor

 

摘要:

The earlier reported matrix system methylacetate/ H2O/Ar has been reinvestigated by IR spectroscopy. The complex band pattern of the ester νc=0and the water ν3, ν1and ν2modes can be explained by the coexistence of 1:1, linear 1:2 and linear 2:1 H-bonded complexes. The study of methyl benzoate/H2O/Ar supports the proposed interpretation.

 

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