Contributions to the Mechanism of Isobutene Polymerization. V. Effect of Cyclic Olefins
作者:
J.P. Kennedy,
S. Bank,
R.G. Squires,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1967)
卷期:
Volume 1,
issue 6
页码: 961-975
ISSN:0022-233X
年代: 1967
DOI:10.1080/10601326708053750
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The effect of various cyclic and bicyclic olefins on the yield (rate) and molecular weight of polyisobutene has been investigated. Cyclic olefins were found to be both rate poisons and transfer agents and the corresponding coefficients appear to be a function of ring size. Alkyl and aryl substitution on the ring increases both the poison and transfer coefficients. With bicyclic olefins, norbornene and norbornadiene both show moderate and similar poison coefficients, but only the former exhibits transfer activity. These coefficients have been discussed in terms of the allylic termination hypothesis and the known geometry and steric effects of the various rings studied.
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