Surface charge and specific ion adsorption effects in photoelectrochemical devices
作者:
P. Singh,
R. Singh,
R. Gale,
K. Rajeshwar,
J. DuBow,
期刊:
Journal of Applied Physics
(AIP Available online 1980)
卷期:
Volume 51,
issue 12
页码: 6286-6291
ISSN:0021-8979
年代: 1980
DOI:10.1063/1.327616
出版商: AIP
数据来源: AIP
摘要:
The importance of specific ion adsorption and surface charge effects in the design and operation of photoelectrochemical (PEC) devices is demonstrated by experimental data on then‐GaAs/electrolyte andn‐Si/electrolyte interface. The electrolyte chosen for the present study was an ambient temperature molten salt comprising mixtures of aluminum chloride andn‐butyl pyridinium chloride in varying molar ratios. A direct correlation between specific adsorption effects and photovoltaic output parameters is presented for then‐GaAs PEC system. Evidence for specific adsorption of Cl−ions in this system is found in the systematic shift observed in flat‐band potentialsVfbtowards negative values with increasing concentration of free Cl−ions in the AlCl3‐BPC electrolyte. The magnitude of the slope ofVfbversuspCl (=−log[Cl−]) plots [∼0.13 V or 2(2.3kT/q) V] is consistent with that expected from Esin‐Markov adsorption behavior. Anomalous PEC behavior is observed at then‐Si/AlCl3‐BPC interface brought about by modifications in electrostatics across the electrode/electrolyte interphasial region. These modifications arise from either specific adsorption effects or by electrodeposition of aluminum on then‐Si electrode surface. Either process results in a net lowering of the band structure inn‐Si on the energy scale relative to the redox levels. An examination of literature data on high‐efficiency PEC systems reveals that similar shifts in the relative positions of the semiconductor energy levels and redox energies may play an important role in ensuring a more favorable photoresponse than that predicted from idealized models.
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