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Zur Reaktion von Dicyclopentadiendiepoxid mit Acrylsäure

 

作者: Günther Heublein,   Astrid Burckhardt,  

 

期刊: Journal für Praktische Chemie  (WILEY Available online 1988)
卷期: Volume 330, issue 1  

页码: 51-56

 

ISSN:0021-8383

 

年代: 1988

 

DOI:10.1002/prac.19883300111

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

On the Reaction of Dicyclopentadiene Diepoxide with Acrylic AcidThe esterification of dicyclopentadiene diepoxide as a bifunctional epoxide with acrylic acid was investigated. The influence of solvent polarity, reaction temperature and the catalytic system used are discussed. It was found, that the reaction rate increased with increasing solvent polarity. By using tertiary amines as catalysts, only a small catalytic effect was observed. On the contrary, a good catalytic effect was achieved with Lewis‐acids. By means of FeCl3, a vinylester containing epoxide groups and CC‐double‐bonds is obtained, which polymerizes via various mec

 

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