Zur Reaktion von Dicyclopentadiendiepoxid mit Acrylsäure
作者:
Günther Heublein,
Astrid Burckhardt,
期刊:
Journal für Praktische Chemie
(WILEY Available online 1988)
卷期:
Volume 330,
issue 1
页码: 51-56
ISSN:0021-8383
年代: 1988
DOI:10.1002/prac.19883300111
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
On the Reaction of Dicyclopentadiene Diepoxide with Acrylic AcidThe esterification of dicyclopentadiene diepoxide as a bifunctional epoxide with acrylic acid was investigated. The influence of solvent polarity, reaction temperature and the catalytic system used are discussed. It was found, that the reaction rate increased with increasing solvent polarity. By using tertiary amines as catalysts, only a small catalytic effect was observed. On the contrary, a good catalytic effect was achieved with Lewis‐acids. By means of FeCl3, a vinylester containing epoxide groups and CC‐double‐bonds is obtained, which polymerizes via various mec
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